Crystal structure of bis(1-butyl-1-methypyrrolidinium) perthiodicarbonate complex - Université de Bordeaux
Article Dans Une Revue Molbank Année : 2024

Crystal structure of bis(1-butyl-1-methypyrrolidinium) perthiodicarbonate complex

Résumé

Bis(1-butyl-1-methypyrrolidinium) perthiodicarbonate was obtained by the reaction of carbon disulfide with 1-butyl-1-methypyrrolidinium acetate ([BmPyrro][Ac]) in the liquid phase. Structural characterization of this original complex was achieved by single-crystal X-ray diffraction (SCXRD) analysis. The asymmetric unit of the title compound, C2S6·2C9H20N, consisted of two crystallographically 1-methyl-1-butyl pyrrolidinium cations and one perthiodicarbonate anion. The complex C2S6·2C9H20N crystallized in the monoclinic space group, C 2/c, and possessed the following cell parameters: a = 16.0970(10) Å, b = 14.7140(9) Å, c = 12.3280(8) Å, α = 90°, β = 112.3730(12)°, γ = 90°, V = 2700.11 Å3, and Z = 8, Z’ = 0.5.
Fichier principal
Vignette du fichier
2024-130.pdf (1.46 Mo) Télécharger le fichier
Origine Publication financée par une institution
licence

Dates et versions

hal-04741907 , version 1 (17-10-2024)

Licence

Identifiants

Citer

Noël Pinaud, Yann Danten, Mathieu Marchivie, Marcel Besnard, Isabel Cabaço, et al.. Crystal structure of bis(1-butyl-1-methypyrrolidinium) perthiodicarbonate complex. Molbank, 2024, 2024 (3), pp.M1849. ⟨10.3390/m1849⟩. ⟨hal-04741907⟩
0 Consultations
0 Téléchargements

Altmetric

Partager

More